Hi. I'm not related to this family.Here is Catherine in 1901:
1901 Census of Canada about Catharn Humphreys Name: Catharn Humphreys Gender: Female Marital Status: Married Age: 38 Birth Day & Month: 27 Nov Birth Year: 1862 Birthplace: Qc Relation to Head of House: Wife Racial or Tribal Origin: French Nationality: Canadian Religion: Methodist Province: Quebec District: Huntingdon District Number: 156 Sub-District: Hemmingford Sub-District Number: F-3 Household Members: Name Age Hiram Humphreys 38b. 22 Jun 1862 Que.; farmer Catharn Humphreys 38 -wife- b. 27 Nov 1862 Que. Francis Humphreys 11 -son- b. 20 Jan 1890 Que. Samuel Humphreys 10 -son- b. 21 Mar 1891 Que. Jennie Humphreys 8-dau- b. 15 Apr 1892 Que. Joseph Humphreys 7-son- b. 9 Dec 1893 Que. Julius Humphreys 4-son- b. 27 Jan 1897 Que.
Here are baptisms for the children from the Quebec, Vital and Church Records (Drouin Collection), 1621-1967:
Samuel John, son of Hiram J. and Catherine Jane Humphries was b. 21 Mar 1891 and baptized 22 Jul 1895 Hemmingford (Presbyterian Church and Church of England).
Jennie McIntyre, daughter of Hiram J. and Catherine Jane Humphries was b. 15 Apr 1892 and baptized 22 Jul 1895 Hemmingford (Presbyterian Church and Church of England).
Joseph Edgar, son of Hiram J. and Catherine Jane Humphries was b. 9 Nov 1893 and baptized 22 Jul 1895 Hemmingford (Presbyterian Church and Church of England).
Julius Walter, son of Hiram John Humphreys, farmer of the township of Hemmingford.. and Catharine Jane Laware, his wife, was born 27 Jan 1897 and baptitzed 30 Dec 1899Hemmingford (Presbyterian Church and Church of England).
As for the McIntyre connection there is a burial record that might be related to your family:
Jane McIntyre, widow of Joseph Laware, deceased, of the township of Hemmingford, County of Huntingdon, died 13 Apr 1902, and buried 15 Apr 1902 Hemmingford (Presbyterian Church and Church of England). Witnesses: Maggie Laware & Susie Laware.
Here is a death record for witness Maggie:
Vermont Death Records, 1909-2008 about Maggie Laware Downs Name: Maggie Laware Downs [Maggie Laware Laware] Gender: Female Birth Date: 26 Aug 1862 Birth Location: Herringford, Canada Death Date: 30 Jul 1920 Death Location: Bennington, Bennington Cause of Death: Apoplexy Mother's Maiden Name: McIntyre Mother's Name: Jennie McIntyre, b. Canada Father's Name: Joseph Laware, b. Canada Vital Event Type: Certificate of Death https://familysearch.org/pal:/MM9.1.1/VNRQ-GWM
Here is her marriage:
"Vermont, Vital Records, 1760-1954," Joseph Laware in entry for Albert Martin Downs and Margaret Laware (1905)
Name: Margaret Laware Event: Marriage Event Date: 18 Dec 1905 Event Place: , , Vermont, United States Gender: Female Age: 40 Estimated Birth Year: 1865 Quebec Father: Joseph Laware, b. St. Johns, Canada Mother: Jane Mcintyre, b. Canada Spouse: Albert Martin Downs Spouse's Father: Spouse's Mother: Film Number: 540113 Digital Folder Number: 004116166 Image Number: 04075 https://familysearch.org/pal:/MM9.1.1/XF92-CWM Joseph & Jane may also have had a child named Mary Alice:
"Vermont, Vital Records, 1760-1954," Joseph Laware in entry for Mary Alice Laware (1929)
Name: Mary Alice Buss Event: Death Event Date: 14 Feb 1929 Event Place: Bennington, , Vermont Gender: Female Age: 62 Date of Birth: 15 Mar 1866 Canada Father: Joseph Laware, b. Scotland Mother: Jane Macintyre, b. Canada Spouse: Spouse's Father: Spouse's Mother: Film Number: 1984154 Digital Folder Number: 004703659 Image Number: 02363 https://familysearch.org/pal:/MM9.1.1/XFKN-TMF