Re: Marie Melancon / Gaudet/ Brien dit Desrochers
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The reason you could not locate the record of Marie Melancon's first marriage was that she married Octave Gaudet just over the Quebec/Ontario at LaPasse, Ontario. This should solve your mystery:
Marie Melancon, the daughter of Eusebe Melancon and Julie Marion, and Octave Gaudet, the son of Charles Gaudet and Isabelle Marion, were marred at La Passe, Ontario, 10 May 1867.