I have some info from The OUELLETTE Dictionary. However, it's a bit confusing, I don't know how the first marriage can come before the second. This is the reason I tell everybody to verify, verify, verify.
Narcisse OUELLET (son of Pierre OUELLET & Modeste MORNEAU) married (1) on 20 Aug 1867 at St-Roch-de Quebec to Christine BRILLIANT (daughter of Germain BRILLIANT & Judith LEBEL).
Married (2) on 7 Jul 1831 at St-Roch-des-Aulnaies to Rosalie PELLETIER (daughter of Joseph PELLETIER & Joseph DESAINT-ST-PIERRE. I think that is supposed to be JOSEPHTE.