Samuel's will was lost along with many others in Warwick County, Virginia. Grace Hollis Puryear, in her book on the Puryears, states that there are court records to show sons Samuel(the older) and John (Sr.) to be the executors of their father's estate.
Samuel (the older)'s will dated 4/10/1810 and proved 12/7/1810 is recored in Will Book 7-5 of Mecklenburg County, Virginia. Executors are sons Peter and John (Jr.).
John (Jr.) no will has been found. Letters gathered by Grace Hollis Puryear and described in her book, show Achilles to be a son of this man.