I show Cicely Ann (born 1/30/1821) to be the daughter of William H. and Mary C. A. Puryear who were married 1/26/1813 in Virginia. Other children were Edward S. (1/10/1815-after 1870) and William A. (5/28/1828 - after 1870).
William H. Puryear is a son of Reuben(9/15/1762-8/30/1838) and Nancy (2/28/1763-after 3/4/1843)Puryear who were married 5/13/1786 in Hanover County, Virginia. Reuben was a Revolutionary Soldier and received a pension for hia service.
Reuben Puryear is a son of Thomas (about 1725-1762) and Margaret Bowles Puryear.
Some researchers show Thomas to be a son of Samuel and Elizabeth Puryear. My research has not found a connection other than dates and location.