Re: Cicely A. Puryear-Virginia
The William E. Puryear you found is a third cousin of Cicely.
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Cicely's brother Edward is in the 1850 census for Fluvanna County, the 1860 census for Buckingham County, and the 1870 census for Nelson County.
Her brother William is in the 1870 census for Buckingham County.
Cicely's mother is living with her sister-in-law, Sally A. Puryear Cobb,in the 1850 census for Buckingham County. Sally's husband William Cobb seems to have died before 1850 census.
Good luck in your search!!