Re: Arsenault/Mexico, Maine
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It seems Joyce found the right family for you. As you wanted to connect them to PEI, I looked for them in 1911 Canada census - 1920 census said they immigrated in 1904 so they should be there.
This seems to fit
1911 SUB DISTRICT 21-LOT 15, PRINCE, PRINCE EDWARD ISLAND, CANADA
Leon, age 60, farmer born 1851 (cannot read month)
Henriette , age 55, wife, born March 1856
Roseline, age 21, daughter, born May 1881
Clement, age 18, son, born Nov. 1893
Ursulle, age 15, daughter, born Sept. 1896
Lucien, age 13, son, born Sept. 1898
Jean, age 11, son, born June 1900
Emaunnuel, age 9, son, born Nov. 1902
all are born PEI
so they were from PEI as you thought.