Since yours is an old posting I'm sure someone else has told you by now but just in case they haven't, Levi Peal b. 1811 and wife Queen E Lester are both buried in Shawnee Cemetery, Benton Co MO. He didn't die in KY in 1863 as you have posted. Other family members buried there as well. The transcriptions are online through Look to the Past or just by googling Shawnee Cemetery, Benton Co MO.
My only connection is his son Enoch F Peal born 4 Dec 1851 in Benton Co MO who married on 26 Feb 1871 Virginia Wickliffe. I do have info on that.