I think I found your James. Born Monroe Co., Ohio, c1863, married Wirt Co., W. Va., 12-16-1885 to Clara L. Enoch, born c1866, the daughter of T.S. enouch & N.S. Enoch. I have nothing on 2nd marriage or children. I would be interested in this info. I have as his siblings:Mary L.,b.1885 OH
Franklin Pierce,b.3-1859 d.4-19-1935
Lucy C.,b.1862 OH
Joseph N.,b.c1868 OH
John B.,b.1871 IN
Annette,b. 6-9-1873 OH
Jacob E.,b.1877 WV
Leander,b.11-19-1879 WV d.1940 OH
His parents were: Benjamin Provance, b.2-9-1834, PA, d.6-23-1908, OH and married 1st Eunice Cline, b.4-24-1838, d.12-27-1875. Married 2nd in Wirt Co., WV, Catherine Bates, b.c1834, OH, d.1918.
Bemjamin's parents were James Provance, b.8-25-1809, d.9-13-1894 & Susanna Spencer, b.12-19-1810, d.4-20-1883. She was a step-sister to Benjamin's father David. He married her widowed mother Rachel Reed Spencer. Ben & Susanna had 14 children, mostly born in PA, VA & OH. James' parents were David, b.8-8-1788, PA, 1st married Agnes Hartley, b.1790. Married 2nd Mrs. Sarah Howard and 3rd, Edith ?. I have 14 children shown, mostly by Agnes. David's parents were Joseph Yard Provance, b3-31-1764, d.5-16-1843, married 1st Margaret Elizabeth Castro, b.1765, d.3-30-1818. Married 2nd Rachel Reed Spencer, b.1-12-1783, d.3-4-1867. I show 23 children but the number varies..my first list does not show Susanna, who we know married James.
If this is what you're looking for I have more info but Joseph Yard Provance info is easy to come by. His father is John William Province & Sarah Yard Wright and there it gets tricky.